In 1911, Dutch scientist Heike Kamerlingh Onnes discovered a process thought to be the closest approximation to a perpetual motion machine found in nature. He found that superconductivity, or zero electrical resistance, could be achieved using certain alloys and chemical compounds that lost all of their electrical resistance when cooled close to absolute zero — in his case, 4.19 Kelvin (K) for liquid mercury. (Absolute zero is 0 Kelvin, -273 degrees Celsius, or -459 degrees Fahrenheit.) In subsequent decades, superconductivity was found in lead at 7 K, in niobium at 10 K, and in niobium nitride at 16 K.
For the next three-quarters of a century, progress on finding compounds that conducted at higher, more practical temperatures, was excruciatingly slow. New materials discoveries typically only improved conductive temperatures by a fraction of a degree. And then, circa 1973, even incremental progress seemed to stall out, having peaked at 23 K with another niobium-based material. Superconductivity was seen by many as a theory with little hope of practical applications.
Then, in 1983, Bednorz and Müller noticed that perovskites, a class of oxides, offered the promise of conducting electricity at more achievable temperatures. To obtain a chemically stable material, the duo added barium to crystals of lanthanum-copper-oxide to produce a ceramic that eventually became the first successful high-temperature superconductor. The revelation was initially greeted with skepticism because ceramics were generally considered insulators, not conductors, but the new material withstood repeated testing to demonstrate superconductivity at 35 K.
The simplest and most practical significance was that 35 K requires less cooling with liquid helium (4.2 K), which is a very limited resource. Superconductors with transition temperatures above 77 K can be cooled with liquid nitrogen, which can be relatively easily condensed out of air by refrigeration techniques. This makes the cooling process easier and less expensive. The other practical aspect of the higher temperature discovery was that it revealed a different model for superconductivity, which opened a whole field of research into whether room-temperature superconductivity might someday be attainable.