The Rational User Education Youtube channel posted a great playlist recently, entitled: Installing and Configuring IBM Rational CLM Applications. With 14 videos, we're sure you'll find some great information to help with your deployment of CLM!
CLM 2012 Deployment Guide: https://jazz.net/library/article/832/
Key Installation info: http://goo.gl/O6qEb
Performance Tips: http://goo.gl/KCIWp
Exporting from IBM Rational DOORS: https://jazz.net/library/article/1243